Dr. Sebastian Arndt

 

Johannes Gutenberg-University Mainz
Department of Chemistry
Duesbergweg 10–14
Room 2125-00/321
55128 Mainz
Phone: +49 6131/39-27604
E-mail: sarndt@uni-mainz.de
2009–2012 Bachelor Studies in Chemistry at Heidelberg University
2012 Bachelor Thesis in the Hashmi group at Heidelberg University
2012–2015 Master Studies in Chemistry at Heidelberg University
2012–2013 Research intership in the Bedford Group at University of Bristol (England)
2014–2015 Master Thesis in the Lautens group at University of Toronto (Canada)
2015–2018 PhD studies in the Hashmi group at Heidelberg University
2016 Research intership in the Suginome Group at University of Kyoto (Japan)
2018 Research intership in the Hyland Group at University of Wollongong (Australia)
Since 2018 PostDoc in the Waldvogel group
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Research interests: electroorganic synthesis, renewable resources
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Publications:

S. Arndt, M. Rudolph, A. S. K. Hashmi, The Gold(I)-Mediated Domino Reaction to Fused Diphenyl Phosphoniumfluorenes: Mechanistic Consequences for Gold-Catalyzed Hydroarylations and Application in Solar Cells, Chem. - Eur. J. 2018, 24, 7882–7889.
[DOI: 10.1002/chem.201800460] (front graphic)

S. Arndt, M. Rudolph, A. S. K. Hashmi, Gold-based frustrated Lewis acid/base pairs (FLPs), Gold Bull 2017, 50, 267–282.
[DOI: 10.1007/s13404-017-0219-7]

S. Arndt, M. M. Hansmann, M. Rudolph, F. Rominger, A. S. K. Hashmi, Direct Access to π-Extended Phosphindolium Salts by Simple Proton-Induced Cyclization of (o-Alkynylphenyl)phosphanes, Chem.- Eur. J. 2017, 23, 5429–5433.
[DOI: 10.1002/chem.201700889]

S. Arndt, M. M. Hansmann, P. Motloch, M. Rudolph, F. Rominger, A. S. K. Hashmi, Intramolecular anti-Phosphinoauration of Alkynes: An FLP-Motivated Approach to Stable Aurated Phosphindolium Complexes, Chem.- Eur. J. 2017, 23, 2542–2547.
[DOI: 10.1002/chem.201605914]

A. H. Bagi, Y. Khaledi, H. Ghari, S. Arndt, A. S. K. Hashmi, B. F. Yates, A. Ariafard, A Mechanistic Investigation of the Gold(III)-Catalyzed Hydrofurylation of C–C Multiple Bonds, J. Am. Chem. Soc. 2016, 138, 14599–14608.
[DOI: 10.1021/jacs.6b05742]

C. Bürki, A. Whyte, S. Arndt, A. S. K. Hashmi, M. Lautens, Expanding the Scope of the Gold(I)-Catalyzed Rautenstrauch Rearrangement: Protic Additives, Org. Lett. 2016, 18, 5058–5061.
[DOI: 10.1021/acs.orglett.6b02505]

T. Lauterbach, S. Arndt, M. Rudolph, F. Rominger, A. S. K. Hashmi, Gold Catalysis: β-Ketonaphthalenes via Molecular Gymnastics of 1,6-Diyne-4-en-3-ols, Adv. Synth. Catal. 2013, 355, 1755–1761.
[DOI: 10.1002/adsc.201300396]